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Multivariate linear model of the membrane based on fluorescence quenching of the analyte sensor ring ...

eatureParametersofChemicalSensorBasedonFIuorescenceQuenchingforAnalytesLIWei. '. A, CHENJian, XIANGBing-Ren, ANDeng-Kui (1.ResearchCenterforComputerScienceandAnalyticalChemistry,[link widoczny dla zalogowanych], ChinaPharmaceuticalUn ~ ersity,[link widoczny dla zalogowanych], Nanfing210009, Ch / na; 2.SchoolofPharmaceuticalSconce, XinjiangMedicalUnboersity, Urumqi830054, China; 3.TheKeyLaboratoryofAnalyticalSciencesofMOEandDepartmentofChemistry, XiamenUniversity,[link widoczny dla zalogowanych], Xiamen361005,[link widoczny dla zalogowanych], China) AbstractAmathematica1modelwasdeducedanddescribedforthedifferentmechanismoffluorescencequenchingtoanalyteasedontheessentialquenchingmodelsincludingthedynamicquenching, theresonanceenergytransferandtheinnerfiltereffectsinvolvingabsorptionofbothexcitedlightfromthelightsourceandemittedlightfrommembrane. Themodelreportedhereindicatedthatthelogarithmicfunctionsoftheintensityoffluorescencemodulationinvirtueofmultiplequenchingfactorsconformtotheruleofaddition. Theresponsefeatureparametersofchemicalsensorbasedonfluorescencequenchingforanalysescouldbecalculatedbycombiningthemultivariatelinearmodelwithatri-cupmethod. Aconceptionbasedonregardingthechemicalsensorasthesecondsourceoflightwasadvancedtogetmoreusefulinformationonanalytes. Thepyrenebutyricacidwaschosenasafluoroproheforconstructingthechemicalsensortoresponseaseriesofthetherapeuticdrugs. Atrainofthoughtforconstructingthequantitativeanalysismode1forthechemica1membranesensorasedo11thefluorescencequenchingwasafrordedinthelightoftheexperimentalresults. KeywordsChemicalsensors; Moleculeprobe; Fluorescencequenching; Multivariatelinearmodel (Ed.: K, G)
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